Dynamical Simulation on Formation Process of Methane Hydrate by MD Method

Experimental Measurement of Methane and Ethane Mole Fractions during Gas Hydrate Formation

The super-saturation condition has to be provided to form gas hydrates. Consequently, the prediction of the guest molecule fraction in the aqueous phase is crucial in the study of the gas hydrate kinetics. In the present work, several experiments were carried out in a semi-batch reactor in order to determine the mole fraction of methane and ethane during gas hydrates formation (growth stage...

Modeling of Methane Hydrate Decomposition by Using Chemical Affinity

In this work, experimental kinetics data of methane hydrate decomposition at temperatures ranging from 272.15 to 276.15 K and at pressures ranging from 10 to 30 bars were modeled by using chemical affinity. This model proposed a macroscopic model which is independent of any intermediate mechanism like heat or mass transfer. The results show there is good agreement with experimental data. Al...

Effect of Surfactants on Methane Hydrate Formation and Dissociation APPROVED BY SUPERVISING COMMITTEE:

Formation of methane hydrate from polydisperse ice powders.

Neutron diffraction runs and gas-consumption experiments based on pressure-volume-temperature measurements are conducted to study the kinetics of methane hydrate formation from hydrogenated and deuterated ice powder samples in the temperature range of 245-270 K up to high degrees of transformation. An improved theory of the hydrate growth in a polydisperse ensemble of randomly packed ice sphere...

Thermal conductivity of methane hydrate from experiment and molecular simulation.

A single-sided transient plane source technique has been used to determine the thermal conductivity and thermal diffusivity of a compacted methane hydrate sample over the temperature range of 261.5-277.4 K and at gas-phase pressures ranging from 3.8 to 14.2 MPa. The average thermal conductivity, 0.68 +/- 0.01 W/(m K), and thermal diffusivity, 2.04 x 10(-7) +/- 0.04 x 10(-7) m2/s, values are, re...